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Large Polarization and Susceptibilities in Artificial Morphotropic Phase Boundary PbZr1− xTixO3 Superlattices

Publication Type

Journal Article

Authors

Lupi, E, A Ghosh, S Saremi, S.-L Hsu, S Pandya, G Velarde, A Fernandez, Ramamoorthy Ramesh, L.W Martin

DOI

10.1002/aelm.201901395

Abstract

The ability to produce atomically precise, artificial oxide heterostructures allows for the possibility of producing exotic phases and enhanced susceptibilities not found in parent materials. Typical ferroelectric materials either exhibit large saturation polarization away from a phase boundary or large dielectric susceptibility near a phase boundary. Both large ferroelectric polarization and dielectric permittivity are attained wherein fully epitaxial (PbZr0.8Ti0.2O3)n/(PbZr0.4Ti0.6O3)2 n (n = 2, 4, 6, 8, 16 unit cells) superlattices are produced such that the overall film chemistry is at the morphotropic phase boundary, but constitutive layers are not. Long- (n ≥ 6) and short-period (n = 2) superlattices reveal large ferroelectric saturation polarization (Ps = 64 µC cm−2) and small dielectric permittivity (εr ≈ 400 at 10 kHz). Intermediate-period (n = 4) superlattices, however, exhibit both large ferroelectric saturation polarization (Ps = 64 µC cm−2) and dielectric permittivity (εr = 776 at 10 kHz). First-order reversal curve analysis reveals the presence of switching distributions for each parent layer and a third, interfacial layer wherein superlattice periodicity modulates the volume fraction of each switching distribution and thus the overall material response. This reveals that deterministic creation of artificial superlattices is an effective pathway for designing materials with enhanced responses to applied bias. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Journal

Advanced Electronic Materials

Volume

Year of Publication

2020

ISSN

2199160X

Notes

cited By 1

Research Areas

Ramesh Lab