FTIR spectroscopy of metal oxide insertion materials: Analysis of LixMn2O4 spinel electrodes

Publication Type

Journal Article

Date Published

05/1997

Authors

DOI

Abstract

Fourier transform infrared (FTIR) spectra were obtained from spinel-type lithium manganese oxides of composition LixMn2O4 with 0 < x < 2.4, prepared by both chemical and electrochemical means. Each phase in this system has a distinct spectrum which is characteristic of the local (shortrange) structure. Mixtures of phases were analyzed using the method of scaled absorbance subtraction. The results correlate well with previously reported XRD and neutron diffraction analyses as well as with phase behavior indicated by electrochemical measurements. FTIR spectroscopy thus provides both qualitative and quantitative information and is shown to be an effective companion technique to X-ray diffraction.

Journal

Materials Research Bulletin

Volume

32

Year of Publication

1997

Issue

5

ISSN

00255408

Organization