Modeling, Simulation, and Implementation of Solar-Driven Water-Splitting Devices

Publication Type

Journal Article

Date Published

10/2016

Authors

DOI

Abstract

An integrated cell for the solar-driven splitting of water consists of multiple functional components and couples various photoelectrochemical (PEC) processes at different length and time scales. The overall solar-to-hydrogen (STH) conversion efficiency of such a system depends on the performance and materials properties of the individual components as well as on the component integration, overall device architecture, and system operating conditions. This Review focuses on the modeling- and simulation-guided development and implementation of solar-driven water-splitting prototypes from a holistic viewpoint that explores the various interplays between the components. The underlying physics and interactions at the cell level is are reviewed and discussed, followed by an overview of the use of the cell model to provide target properties of materials and guide the design of a range of traditional and unique device architectures.

Journal

Angewandte Chemie International Edition

Volume

55

Year of Publication

2016

Issue

42

Organization

Research Areas